The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Nitrogen oxides / NO2 / Gierczak(1999)_259-385K_413.4nm

DATAFILE: NO2_Gierczak(1999)_259-385K_413.4nm.txt
NAME: nitrogen dioxide
FORMULA: NO2
AUTHOR(YEAR): Gierczak(1999)
T: 259-385K
λ: 413.4nm
BIBLIOGRAPHY: T. Gierczak, J.B. Burkholder, and A.R. Ravishankara, "Temperature dependent rate coefficient for the reaction
O(3P) + NO2 → NO + O2", J. Phys. Chem. A 103, 877-883 (1999); DOI: 10.1021/jp983962p
COMMENTS: The absorption cross section at 413.4 nm was determined as a function of temperature using the chemical titration and flow methods. Including the low-temperature data of

J.W. Harder, J.W., J.W. Brault, P.V. Johnston, and G.H. Mount, "Temperature dependent NO2 cross sections at high spectral resolution", J. Geophys. Res., 102, 3861-3879 (1997); DOI: 10.1029/96JD03086,

the temperature-dependent (200-400 K) absorption cross section is given by

σ(413.4 nm, T) = (9.49 - 0.00549 T) ×10-19 cm2 molecule-1

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